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Primary Lithium batteries feature with high energy density and long sheftlife and excellent for smoke alarm, multi-meter and LED lighting etc application. However they are not rechargeable and totally different with Li-Ion batteries. If you are looking for rechargeable Lithium-Ion batteries, please follow this link: Li-Ion Battery section. There are three types of chemistries in Lithiun promary battery, which result in different voltage as the follows: